(R)-(+)-2,2'-Diamino-1,1'-binaphthalene

(R)-(+)-2,2'-Diamino-1,1'-binaphthalene

Cat Number
INT18741850
CAS Number
18741-85-0

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CAS Number
18741-85-0
EINECS
628-471-3
Storage
Keep in dark place, sealed in dry, room temperature
Synonyms
(R)-(+)-1,1''-BINAPHTHALENE-2,2''-DIAMINE (R-BINAM) ((R)-(+) -2,2''-DIAMINO-1''1-BINAPHTHYL);(R)-(+)-1,1μ-Binaphthalene-2,2μ-diamine,(R)-(+)-2,2μ-Diamino-1,1μ-binaphthalene,(R)-(+)-DABN;(R)-(+)-1,1μ-Bi(2-naphthylamine),(R)-(+)-1,1μ-Binaphthalene-2,2μ-diamine,(R)-(+)-2,2μ-Diamino-1,1μ-binaphthalene,(R)-(+)-DABN;(aR)-1,1'-Binaphthalene-2,2'-diamine;(aR)-2,2'-Diamino-1,1'-binaphthalene;(R)-BINAM;[aR,(+)]-1,1'-Binaphthalene-2,2'-diamine;(R)-(+)-1,1'-BINAPHTHYL-2,2'-DIAMINE, 99 % (99% EE/GLC)
Description
(R)-(+)-1,1'-Bi(2-naphthylamine) derivatives have been used for asymmetric hydrogenations, cyclopropanations and formation of chiral lactones. It can be used for the synthesis of sterically hindered binaphthalene-based monophosphane ligands.
Molecular Formula
C20H16N2
Molecular Weight
284.35
Appearance
Powder
Melting Point
242-244 ℃
Boiling Point
416.85 ℃ (rough estimate)
Color
slightly beige
pKa
3.79±0.10(Predicted)
Purity
0.99
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